Are your option settings respected if you print from the command line, for example
lpr -o Duplex=DuplexNoTumble ColorMode=ICM file.pdf
What happens if you choose "Export to PDF" in the "File" menu of LibeOffice and print the saved PDF file with evince afterwards?
Are your option settings respected if you print from the command line, for example
lpr -o Duplex= DuplexNoTumble ColorMode=ICM file.pdf
What happens if you choose "Export to PDF" in the "File" menu of LibeOffice and print the saved PDF file with evince afterwards?